PENGARUH KATALIS CaCO3 PADA PROSES PACK CARBURIZING TERHADAP KEKERASAN BAJA KARBON, A REVIEW
DOI:
https://doi.org/10.31328/ciastech.v6i1.5359Keywords:
Pack Carburizing, Katalis CaCO3, Baja Karbon RendahAbstract
Pesatnya perkembangan teknologi membuat permintaan produk yang berkualitas tinggi dengan bernilai ekonomis meningkat, salah satunya adalah komponen otomotif yang sering mengalami gesekan sehingga diperlukaan permukaan yang sangat keras untuk menahan laju keausan. Komponen otomotif yang sering mengalami gesekan adalah roda gigi, biasanya roda gigi terbuat dari baja karbon rendah yang sifat mudah dibentuk, tetapi nilai kekerasannya rendah, sehingga nilai kekerasannya harus ditingkatkan. Salah satu metode untuk meningkatkan kekerasan baja karbon rendah adalah karburisasi (Carburizing) dengan cara meningkatkan kandungan karbon pada permukaan material sehingga terbentuk permukaan material yang keras. Cara kerjanya yaitu dengan cara benda kerja dan arang sebagai sumber karbon aktif dimasukkan kedalam kotak, kemudian dipanaskan sampai pada suhu austenisasinya, pada suhu austenisasinya ini akan keluar gas CO2 dan CO, yang akan terurai dan atom karbon akan berdifusi pada permukaan baja. Aktivator atau katalis untuk meningkatkan kecepatan reaksi, dengan tingginya reaksi yang terjadi maka karbon yang berdifusi semakin banyak dan kekerasan semakin meningkat. Katalis yang mudah didapatkan adalah katalis heterogen kalsium karbonat (CaCO3) dari cangkang kerang, yang mana cangkang kerang mengandung kalsium karbonat sekitar 96% CaCO3. Ketika mengalami perlakuan panas CaCO3(s) bereaksi menjadi CaO(s) + CO2(g) dari reakisi tersebut akan meningkatkan CO2.References
R. M. Pikahulan, “Konsep Alih Teknologi Dalam Penanaman Modal Di Indonesia Bidang Industri Otomotif,†Cakrawala Huk., vol. 13, no. 2, pp. 72–88, 2018, [Online]. Available: https://ejournal.up45.ac.id/index.php/cakrawala-hukum/article/view/385/342
K. S. Hassan, “Comparative of wear resistance of low carbon steel pack carburizing using different media,†Int. J. Eng. Technol., vol. 4, no. 1, p. 71, 2015, doi: 10.14419/ijet.v4i1.3866.
W. D. Callister Jr and D. G. Rethwisch, Characteristics, Application, and Processing of Polymers. 2018.
Fox-Rabinovich, George E. Totten. - Steel Heat Treatment Metallurgy and Technologies (2007, Taylor & Francis) - libgen.li.pdf.â€
L. Joska, J. Fojt, M. Hradilova, F. Hnilica, and L. Cvrcek, “Corrosion behaviour of TiN and ZrN in the environment containing fluoride ions,†Biomed. Mater., vol. 5, no. 5, 2010, doi: 10.1088/1748-6041/5/5/054108.
G. Parrish, Carburizing:Microstructures and Properties. 1999. [Online]. Available: http://link.springer.com/10.1007/BF02646170
Ir. Wahid Suherman “Ilmu Logam II - buku ajar Institute Teknologi Sepuluh November, 1998.â€
I. Mon, Yerimadesi, and Hardeli, “Kimia Fisika (Kinetika Kimia).†p. 32, 2012. [Online]. Available: http://repository.unp.ac.id/26756/1/2012-Buku kinetika kimia %28Yerimadesi%2C dkk%29 1.pdf
O. Adedipe et al., “Explicit microstructural and electrochemical study of value-added carburized mild steel with coconut shell ash and CaCO3 nanoparticles derived from periwinkle shell,†Chem. Data Collect., vol. 45, no. March, p. 101028, 2023, doi: 10.1016/j.cdc.2023.101028.
N. Thammachot, P. Nachaisit, W. Homjabok, C. Peeratatsuwan, and A. Mayai, “The Effects of Energizer, Carburizing Temperature and Time on the Mechanical Properties of Hardened Big Knives in a Pack Carburizing process,†KKU Eng. J., vol. 43, no. December, pp. 172–177, 2016, doi: 10.14456/kkuenj.2016.33.
O. Akanji, O. Fatoba, and A. Aasa, “The Influence of Particle Size and Soaking Time on Surface Hardness of Carburized AISI 1018 Steel,†Br. J. Appl. Sci. Technol., vol. 7, no. 1, pp. 37–44, 2015, doi: 10.9734/bjast/2015/13552.
M. Zhao et al., “An efficient salt-thermo-carburizing method to prepare titanium carbide coating,†Surf. Coatings Technol., vol. 465, no. March, p. 129546, 2023, doi: 10.1016/j.surfcoat.2023.129546.
A. Karim, I. Azmy, S. Q. Khoiriah, and C. Bintoro, “Microstructure and Mechanical Properties of Pack Carburized AISI 1020 Steel Using Na2CO3 and CaCO3 Catalysts,†J. Renew. Energy Mech., vol. 5, no. 02, pp. 52–59, 2022, doi: 10.25299/rem.2022.vol5(02).9965.
O. Adedipe et al., “Unveiling high-performance carburized mild steel using coconut shell ash and CaCO3 nanoparticles derived from periwinkle shell,†Int. J. Adv. Manuf. Technol., vol. 126, no. 9–10, pp. 4711–4721, 2023, doi: 10.1007/s00170-023-11399-w.
E. K. Arthur and S. T. Azeko, “Surface hardening of ferrous materials with cassava (Manihot spp.) waste: A review,†Sci. African, vol. 9, p. e00483, 2020, doi: 10.1016/j.sciaf.2020.e00483.
S. A. Afolalu, E. H. Asonaminasom, S. O. Ongbali, A. A. Abioye, M. O. Udo, and E. Y. Salawu, “Dataset on experimental investigation of optimum carburizing temperature and holding time of bi- nano additives treatment of AISI 5130 steel,†Data Br., vol. 19, pp. 2279–2283, 2018, doi: 10.1016/j.dib.2018.07.025.
G. Wang, X. Sang, Y. Zhang, M. H. Zhao, G. T. Xu, and Z. Peng, “Carburization-induced microstructure evolution and hardening mechanism of 18CrNiMo7-6 steel,†J. Mater. Res. Technol., vol. 25, pp. 1649–1661, 2023, doi: 10.1016/j.jmrt.2023.06.050.
Bahtiar, M. Iqbal, and D. Arisandi, “Analisis Kekerasan Dan Struktur Mikro Pada Baja Komersil Yang Mendapatkan Proses Pack Carburizing Dengan Arang Cangkang Kelapa Sawit,†J. Mek., vol. 8, no. 1, pp. 686–696, 2017.
O. Adedipe et al., “Explicit microstructural and electrochemical study of value-added carburized mild steel with coconut shell ash and CaCO 3 nanoparticles derived from periwinkle shell,†Chem. Data Collect., vol. 45, no. March, p. 101028, 2023, doi: 10.1016/j.cdc.2023.101028.
S. Dampang, E. Purwanti, F. Destyorini, S. B. Kurniawan, S. R. S. Abdullah, and M. F. Imron, “Analysis of Optimum Temperature and Calcination Time in the Production of CaO Using Seashells Waste as CaCO3 Source,†J. Ecol. Eng., vol. 22, no. 5, pp. 221–228, 2021, doi: 10.12911/22998993/135316.
H. Hafni, S. Hadi, and E. Edison, “The Influence of Calcium Carbonate Composition and Activated Carbon in Pack Carburizing Low Carbon Steel Process in the Review of Hardness and Micro Structure,†IOP Conf. Ser. Earth Environ. Sci., vol. 97, no. 1, 2017, doi: 10.1088/1755-1315/97/1/012037.
T. J. Irwanto and A. Irmawan, “Pengaruh Pemanfaatan Limbah Kulit Kerang Bambu Sebagai Pengganti Sebagian Semen Terhadap Kuat Tekan Beton dengan Penggunaan Agregat Kasar Madura,†Ge-STRAM J. Perenc. dan Rekayasa Sipil, vol. 4, no. 1, pp. 21–26, 2021, doi: 10.25139/jprs.v4i1.3360.
S. Darmo, R. Soenoko, E. Siswanto, and T. D. Widodo, “Study on mechanical properties of pack carburizing SS400 steel with energizer pomacea canalikulata lamarck shell powder,†Int. J. Mech. Eng. Technol., vol. 9, no. 5, pp. 14–23, 2018, doi: 10.30574/gjeta.2022.11.2.0087.
A. González-Angeles, J. López-Cuevas, and N. Pitalúa-DÃaz, “Comparison of CaCO3 from natural sources and artificial carbonates as activators of solid-phase carburizing of low-carbon steel,†Met. Sci. Heat Treat., vol. 55, no. 7–8, pp. 355–357, 2013, doi: 10.1007/s11041-013-9634-4.
T. Guo, X. Cao, H. Shao, Q. Zhao, and Z. Liang, “Effect of Fe on the oxidation, sulfidation and carburization behaviors of alloys in CO2 containing SO2,†Corros. Sci., vol. 222, no. August, p. 111438, 2023, doi: 10.1016/j.corsci.2023.111438.
N. Xiao, W. Hui, Y. Zhang, X. Zhao, Y. Chen, and H. Dong, “High cycle fatigue behavior of a low carbon alloy steel: The influence of vacuum carburizing treatment,†Eng. Fail. Anal., vol. 109, no. September 2019, p. 104215, 2020, doi: 10.1016/j.engfailanal.2019.104215.
P. A. Ihom, “Case hardening of mild steel using cowbone as Energiser,†African J. Eng. Res., vol. 1, no. October, pp. 97–101, 2013.
N. Shell, W. Powders, and C. Duration, “Effective Case Depth and Wear Resistance of Pack Carburized,†2022.
Ramli, C. C. Wu, and A. Shaaban, “Mechanical properties of pack carburized scm 420 steel processed using natural shell powders and extended carburization time,†Crystals, vol. 11, no. 9, 2021, doi: 10.3390/cryst11091136.
T. Dwi Susanto, N. Rekto Prabowo, and B. Darmawan, “Intuisi Teknik dan Seni Efektifitas Katalis Proses Pack Carburizing Terhadap Kekerasan Permukaan dan Struktur Mikro Baja ST 42 The Effectiveness of Pack Carburizing Catalyst Against Surface Hardness and Microstructure of ST 42,†vol. 12, no. 2, pp. 29–39, 2020.
R. Umunakwe, O. C. Okoye, C. I. Madueke, and D. O. Komolafe, “Effects of Carburization with Palm Kernel Shell/Coconut Shell Mixture on the Tensile Properties and Case Hardness of Low Carbon Steel,†FUOYE J. Eng. Technol., vol. 2, no. 1, 2017, doi: 10.46792/fuoyejet.v2i1.83.
